That boundaries can be changed so easily was not entirely a surprise to researchers, who used spinning arrays of magnetic particles to see what they suspect is happening at the interface between misaligned crystal domains.
According to Sibani Lisa BiswalProfessor of Chemical and Biomolecular Engineering at Rice’s George R. Brown School of Engineeringand doctoral student and lead author Dana Lobmeyer, interface shear at the boundary between crystal and void can really drive how microstructures develop.
The technology reported in The progress of science can help engineers design new and improved materials.
To the naked eye, ordinary metals, ceramics and semiconductors seem uniform and solid. But on a molecular scale, these materials are polycrystalline, separated by defects called grain boundaries. The organization of these polycrystalline aggregates controls such properties as conductivity and strength.
During applied stress, grain boundaries can be formed, reconfigured or even disappear completely to meet new conditions. Although colloidal crystals have been used as model systems to see boundaries shift, it has been challenging to control their phase transitions.
“What sets our study apart is that in the majority of colloidal crystal studies, the grain boundaries are formed and remain stationary,” Lobmeyer said. “They are mainly carved in stone. But with our rotating magnetic field, the grain boundaries are dynamic and we can see their movement.”
In experiments, the researchers induced colloids of paramagnetic particles to form 2D polycrystalline structures by spinning them with magnetic fields. As recently shown in a previous studyThis type of system is well suited for visualizing phase transitions that are characteristic of nuclear systems.
Here they saw that gas and solid phases can coexist, resulting in polycrystalline structures that include particle-free regions. They showed that these voids act as sources and depressions for the movement of grain boundaries.
The new study also shows how their systems follow the long-term Read-Shockley theory of hard condensed matter that predicts the misorientation angles and energies of low-angle grain boundaries, those characterized by a slight skew between adjacent crystals.
By applying a magnetic field to the colloidal particles, Lobmeyer caused the iron oxide-embedded polystyrene particles to collect and see how the crystals formed grain boundaries.
“We usually started with many relatively small crystals,” she said. “After a while, the grain boundaries began to disappear, so we thought it could lead to a single, perfect crystal.”
Instead, new grain boundaries were formed due to shear at the cavity interface. Like polycrystalline materials, these followed the misorientation angle and energy predictions made by Read and Shockley more than 70 years ago.
“Grain boundaries have a significant impact on the properties of materials, so understanding how voids can be used to control crystalline materials offers us new ways to design them,” said Biswal. “Our next step is to use this tunable colloidal system to study annealing, a process that involves multiple heating and cooling cycles to remove defects in crystalline materials.”
The National Science Foundation (1705703) supported the research. Biswal is William M. McCardell Professor of Chemical Engineering, Professor of Chemical and Biomolecular Engineering and in Materials Science and Nanotechnology.
Read the summary at https://www.science.org/doi/10.1126/sciadv.abn5715.
This press release is available online at https://news.rice.edu/news/2022/grain-boundaries-go-flow.
Follow Rice News and Media Relations via Twitter @RiceUNews.
Models for molecules show unexpected physics: https://news.rice.edu/news/2022/models-molecules-show-unexpected-physics
Biswal Research Group: https://www.ruf.rice.edu/~biswalab/Biswal_Research_Group/Welcome.html
Chemical and biomolecular technology: https://chbe.rice.edu
George R. Brown School of Engineering: https://engineering.rice.edu
Rice University engineers simulated atomic-scale grain boundaries with magnetic particles to see how the shear stress affected their motion. The video shows new grain boundaries formed due to shear at the interface between crystals and voids, following the error orientation angle and energy predictions made more than 70 years ago. The colors indicate the orientation of the crystals. (Credit: Biswal Research Group / Rice University)
Pictures for download:
A Rice University study reconfigures a polycrystalline material that spins in a magnetic field when grain boundaries appear and disappear due to circulation at the interface between the voids. The different colors identify the crystal orientation. (Credit: Biswal Research Group / Rice University)
Rice University Professor Sibani Lisa Biswal, left, and PhD student Dana Lobmeyer co-authored a study describing how interface shear affects grain boundary motions through colloidal crystals. (Credit: Quan Nguyen / Rice University)
Rice University PhD student Dana Lobmeyer on the custom rig she used to create macro-scale models of shear-induced grain boundary movements and formation. (Credit: Rice University)
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Method of research
Topic for research
Grain boundary dynamics driven by magnetically induced circulation at the void interface of 2D colloidal crystals
Date of publication of the article
June 3, 2022
The authors explain that they have no competing interests.
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